Padmé Amidala (born Padmé Naberrie, secretly known as Padmé Skywalker) is a major character in the Star Wars franchise. She was secretly married to Anakin Skywalker and the mother of the Skywalker twins, Luke and Leia and became an older sister figure towards Anakin's Padawan, Ahsoka Tano.
Star Wars: The Clone Wars
Padmé, who believed her friends to be innocent, became Ahsoka's representative in her trial. Everyone but Anakin had turned against Ahsoka, leaving Padmé sympathetic to her. Padmé won the case due to her husband capturing the real culprit, Barriss Offee. However, it was so in vain because Ahsoka choose to depart from the Jedi Order and find a new life for herself.
As Anakin's padawan, Padmé became an older sister figure to Ahsoka. During the Clone Wars, due to their close relationship with Anakin, Ahsoka and Padmé were the two most important women in Anakin's life. Ahsoka could tell there was a romance going on between Anakin and Padme but never acknowledged that she knew. Padmé defended Ahsoka during her trial, and like Anakin, believed Ahsoka to be innocent.